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Polymethyl methacrylate
PMMA
PMMA
Introduction
Polymethyl methacrylate, which is abbreviated as PMMA, is a clear
plastic, used as a shatterproof replacement for glass. On both sides of
the Atlantic PMMA is also marketed as Plexiglas.
PMMA is more than just plastic and paint. Often lubricating oils and
hydraulic fluids tend to get really viscous and even gummy when they get
really cold. This is a real pain when you're trying to operate heavy
equipment in really cold weather. But when a little bit PMMA is dissolved
in these oils and fluids, they don't get viscous in the cold, and machines
can be operated down to -100 oC (-150 oF), that is,
presuming the rest of the machine can take that kind of cold!
PMMA is a vinyl polymer, made by free radical vinyl polymerization from
the monomer methyl methacrylate.
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| Properties
- hard
- rigid
- transparent (very clear to see through)
- softening point at 125 deg C
- tougher than polystyrene but less tough than ABS (acrylobutylstyrene)
polymer
- absorbs very little visible light but there is a 4% reflection at each
polymer-air interface for normal incident light.
- PMMA is a polar material and has a rather high dielectric constant and
power factor (what is a power factor??) - a good electrical insulator at
low frequencies but less satisfactory at higher frequencies
- good water resistance
- PMMA prepared by free radical polymerization is amorphous and is therefore
soluble in solvents with similar solubility parameters such as benzene,
toluene, chloroform, methylene chloride, esters, ethyl acetate, and amyl
acetate.
- PMMA has good resistance to alkalis (sodium hydroxide, etc.), aqueous
inorganic salts (the Pacific Ocean) and dilute acids.
- PMMA has a better resistance to hydrolysis than PMA probably by virtue of
the shielding of the methyl group.
- PMMA 's outstanding good outdoor weather resistance is remarkably superior
to other thermoplastics.
- When heated about 200 deg C, decomposition becomes appreciable and at 350-
450 deg C, a nearly quantitative yield of monomer is readily obtained. Thus,
the recovery of monomer from scrap is feasible.
- Because it's a thermoplastic, it can be molten and molded (at 100 to 150
deg C) into anything we want.
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Applications
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Grades
- flat yarn
- monofilament
- fibers
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Processability
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POF
is strong and very difficult to bend. There
is only a small loss even when bent to a 25mm radius. Therefore, it can
be installed within walls or other narrow areas. It is also suitable for
lighting in tight locations.
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Installation
work is extremely simple. There
are several methods, but the one common for transmission is the Hot
Plate method. In this method, it takes advantage of the fact that the
material used is plastic, so that fiber ends are heated and softened,
then pushed against a mirrored surface. The process is quick and can be
repeated with very little deviation. Therefore, installation is simple
even for those who have never handled optical fiber.
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Normally,
a 650nm (red) LED is used as the light source for POF optical
transceiver modules. Since
this is within the visible light spectrum, it acts as an eye safety
feature because the user can easily tell when he/she is in danger of
directly viewing the light beam. Also, since 650nm will be the
wavelength used for a large number of DVD light sources, we can expect
the cost to drop even further.
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POF
is not suitable for long-distance transmission. compared
with quartz fiber, there is a large transmission loss. However home and
office applications do not require transmission over great distances,
having a need for ease-of-use, low cost, and stability instead. POF is
best suited for use in these environments.
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Since
POF is strong against vibration and bending,
in addition to its conventional uses in high-speed trains and
automobiles it has also recently been applied to car networks inside the
vehicle due to an increasing multimedia demand from
drivers.
- Since
POF transmits very little infrared light,
it can be used for cold lighting (lighting that do not produce heat),
for semiconductor manufacturing equipment and the lighting displays of
artwork.
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Background information
Principles
of Optical Fiber
Optical fiber transmits light. But, what prevents the light
from escaping from the fiber? The
answer is based on a principle that we experience every
day.
While
swimming at the beach as a child, have you ever thought that you were
safely in shallow water only to be surprised to find that it was too deep
to touch the bottom? When you look straight down into a clear lake or
puddle, you can see its bottom. However, when you view it at an angle and
look off into the distance, the distant scenery is reflected upside down.
This is caused by the difference in the index of refraction between the
water and air, which you probably learned about in grade
school.
Although
optical fiber appears to be only a simple thread, it is actually
composed 2 structures similar to water and air. The area where light
is transmitted is called the core, and the external area is called
the clad.
When
light enters the area between 2 materials with different indexes of
refraction (boundary face), the light will be either entirely
reflected or a portion of it will be refracted, depending on the
angle.
If
the light can be kept at an angle where it is entirely reflected, it
will become trapped inside and transmitted along the
fiber. |
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